Photodegradation of RB5 dye with modified zeolites: influence of temperature and UV irradiation.

José Manuel Sánchez-Viveros, Vitalii Petranovskii, Gregorio Zacahua Tlacuatl, Minerva Lara Hernández, Fernando Chávez–Rivas, Ciro Falcony–Guajardo and Julio César Espinoza–Tapia

Abstract
This study explores the photocatalytic degradation of Reactive Black 5 (RB5) dye using thermally modified natural zeolites, aiming to improve water purification methods. Zeolites were calcined at 250 °C, 350 °C, and 500 °C, and characterized through x–ray diffraction (XRD), Scanning Electron Microscopy (SEM), and Fourier Transform Infrared Spectroscopy (FTIR) to analyze their structural and morphological transformations. The results reveal that calcination significantly enhances the photocatalytic performance, particularly for ZNM500, which exhibited the highest efficiency, reaching a 60% removal rate of RB5. The degradation process follows a pseudo-first-order kinetic model at lower dye concentrations but adheres more closely to the Langmuir–Hinshelwood equation at higher concentrations, emphasizing the role of surface adsorption in catalysis. UV irradiation was a key factor in boosting reaction rates, with shorter wavelengths (254 nm) providing greater energy, leading to more effective dye breakdown by facilitating the generation of reactive hydroxyl radicals (·OH). These findings suggest that thermally modified zeolites, especially ZNM500, represent a promising solution for wastewater treatment, offering an efficient, cost–effective, and environmentally friendly approach to removing synthetic dyes from contaminated water sources.
https://iopscience.iop.org/article/10.1088/2053-1591/ad80ff